Liquid-crystalline fullerodendrimers

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Liquid-crystalline fullerodendrimers which display columnar phases.

[structure: see text] The title compounds were synthesized by applying the 1,3-dipolar cycloaddition reaction of aldehyde-based poly(benzyl ether) dendrimers and sarcosine (N-methylglycine) to [60]fullerene (C(60)). The dendritic building blocks used to functionalize C(60) displayed cubic and hexagonal columnar phases. The fullerene derivatives showed rectangular columnar phases of c2mm symmetry.

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Janus-type liquid-crystalline fullerodendrimers were synthesized via the 1,3-dipolar cycloaddtition of two mesomorphic dendrons and C60. By assembling poly(aryl ester) dendrons functionalized with cyanobiphenyl groups, displaying lamellar mesomorphism, with poly(benzyl ether) dendrons carrying alkyl chains, which display columnar mesomorphism, we could tailor by design the liquid-crystalline pr...

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ژورنال

عنوان ژورنال: New Journal of Chemistry

سال: 2007

ISSN: 1144-0546,1369-9261

DOI: 10.1039/b617671m